tert-Butyl diazoacetate,

Code: 480754-1G D2-231

Application

It is a key starting material in the total synthesis of manzacidin A. It can also be used in the synthesis of diastero- and enantioselective synthesis of 2-vinylc...


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Your Price
€145.00 1G
€178.35 inc. VAT

Application

It is a key starting material in the total synthesis of manzacidin A. It can also be used in the synthesis of diastero- and enantioselective synthesis of 2-vinylcyclopropa[b]indolines from 2-vinylindoles.

tert-Butyl diazoacetate may be used for the preparation of tert-butyl2-(4-chlorophenyl)cyclopropane-1-carboxylate with high enantioselectivity and trans-cis selectivity via cyclopropanation with 4-chlorostyrene in the presence of a chiral (salen)cobalt(III) bromide complex as a catalyst.

New Diazoacetate Formulations

General description

tert-Butyl diazoacetate can be used for numerous organic transformations, including cyclopropanation, insertion, and aziridine-forming reactions. 

Packaging

1 g in glass bottle

bp51-53 °C/12 mmHg (lit.)
density1.026 g/mL at 25 °C (lit.)
impurities≤15% dichloromethane
InChI keyJBVSBLLOZVDAAZ-UHFFFAOYSA-N
InChI1S/C6H10N2O2/c1-6(2,3)10-5(9)4-8-7/h4H,1-3H3
Quality Level100
refractive indexn20/D 1.453 (lit.)
SMILES stringCC(C)(C)OC(=O)C=[N+]=[N-]
storage temp.2-8°C
Cas Number35059-50-8
Hazard Class3
Un Number1993
Pack GroupIII
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